There are several angles of attack here:
1) get an extra 12.5K on a dual format disc by using tracks 5 to 9
1.5) if really desperate another 2.5K can be scavenged: track 1 (40T) mirrored by track 4 (80T) Try to load 4.FOO from track 1 and ON ERROR *LOAD 8.FOO from track 4.
2) The Master Welcome disc has 40 tracks on side 0 and 80 tracks on side 1. So Acorn did made the assumption that 80 tracks means a double sided drive. The disc was converted before use by relinking a directory. For instant booting under DFS the boot loader on drive 0 could try to load a file and ON ERROR *DRIVE 2.
3) A boot loader in track 0 could load the rest of the data itself, massaging the FDC's current-track register if necessary (all through OSWORD &7F.) Like Acorn User's Conv40 but loading straight to memory. This can be combined with copy protection if desired.
4) For huge volumes

consider getting a jig to punch the extra index holes. Any old double sided disc can be made reversible, there's no leaf inside like with 3.5in floppies.
Supposedly an 80T drive can only write dual format content if the disc is unformatted or bulk erased, otherwise the fat heads of a 40T drive pick up two tracks at once and get a bad signal. In which case the 80T drive shouldn't touch track 1.
In passing, dual format discs aren't exactly copy protection but they are a pain to rip

It's getting late, I must be going now.
Discus revertibilis est, neque tempus. Reverte! Reverte!--Greg